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The overall activation for photochemical polymerization is then only about 20 kJ mol 1 . This low value of ER indicates the Rp for photochemical polymerizations will be relatively insensitive to temperature compared to other polymerizations. The effect of temperature on photochemical polymerizations is complicated, however, since most photochemical initiators can also decompose thermally. At higher temperatures the initiators may undergo appreciable thermal decomposition in addition to the photochemical decomposition. In such cases, one must take into account both the thermal and photochemical initiations. The initiation and overall activation energies for a purely thermal self-initiated polymerization are approximately the same as for initiation by the thermal decomposition of an initiator. For the thermal, self-initiated polymerization of styrene the activation energy for initiation is 121 kJ mol 1 and ER is 86 kJ mol 1 [Barr et al., 1978; Hui and Hamielec, 1972]. 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Considerable evidence [Olaj et al., 1977a,b] indicates that the experimentally observed CM may be due in large part to the Diels Alder dimer XII transferring a hydrogen (probably the same hydrogen transferred in the thermal initiation process) to monomer. 3-6b-3 Initiator Transfer Constants.Related: QR Code Generator .NET , Code 39 Generation .NET , .NET Code 128 Generation ean 13 barcode generator javascript Java . BarCode Ean - 13 to String - Stack Overflow
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