vb.net ocr read text from pdf

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There has been enormous commercial success in the synthesis of various copolymers. Intense research activity continues in this area of polymer science with enormous numbers of different combinations of repeating units being studied. Copolymer synthesis offers the ability to alter the properties of a homopolymer in a desired direction by the introduction of an appropriately chosen second repeating unit. One has the potential to combine the desirable properties of two different homopolymers into a single copolymer. Copolymerization is used to alter such polymer properties as crystallinity, exibility, Tm , and Tg . The magnitudes, and sometimes even the directions, of the property alternations differ depending on whether statistical, alternating, or block copolymers are involved. The crystallinity of statistical copolymers is lower than that of either of the respective homopolymers (i.e., the homopolymers corresponding to the two different repeating units) because of the decrease in structural regularity. The melting temperature of any crystalline material formed is usually lower than that of either homopolymer. The Tg value will be in between those for the two homopolymers. Alternating copolymers have a regular structure, and their crystallinity may not be signi cantly affected unless one of the repeating units contains rigid, bulky, or excessively exible chain segments. The Tm and Tg values of an alternating copolymer are in between the corresponding values for the homopolymers. Block copolymers often show signi cantly different behavior compared to alternating and statistical copolymers. Each type of block in a block copolymer shows the behavior (crystallinity, Tm , Tg ) present in the corresponding homopolymer as long as the block lengths are not too short. This behavior is typical since A blocks from different polymer molecules aggregate with each other and, separately, B blocks from

Poly(ethylene terephthalate) Poly(oxyethyleneoxyterephthaloyl)

The last loan created trouble. Some of it was even sold for state bank notes worth only 65 in specie, and this was a yield of 9.25%. Earlier subscribers hastened to demand supplementary stock for the difference. In 1814 the 6s of 1790 declined to a low of 65, to yield 9.22%. These

The IUPAC nomenclature will be used in this book with some exceptions. One exception is the use of well-established, non-IUPAC names for most of the commonly encountered polymers of commercial importance. Another exception will be in not following rule 2 for writing the constitutional repeating unit (although the correct IUPAC name will be employed). Using the IUPAC choice of the CRU leads in some cases to structures that are longer and appear more complicated. Thus the IUPAC structure for the polymer in Eq. 1-3 is

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Before you begin this project, be sure to have all these parts at hand. 1 Casio SA-5 Keyboard 1 miniature N.O. (normally open) pushbutton switch 1 1M potentiometer (mini is best) 2 body-contacts Line-out array as desired (see Appendix A)

although both XXVI and XXVII denote the exact same structure. This type of problem arises only with certain polymers and then only when the drawn structure is to include the ends of the polymer chain instead of simply the repeating unit or the CRU. The CRU will also generally not be used in equations such as Eq. 1-9. The polymerization mechanism in such reactions involves the propagating center on the substituted carbon atom of the monomer. Using

H CH2 C*

By 1935 consols were up to 943 8, to yield 265% They had not stood so high since 1902 By 1939, when World War II broke out, consols had declined to 61, to yield 410% This was just about their low price during the first year of World War I It soon became evident that this was not going to be another 5% war The bank rate was pegged at 2%, and the open market rate of discount remained around 1% Government bond issues were offered at a monotonous 3%, and even these were callable in a comparatively few years Long bonds recovered in the market to 303 319% in 1941 and stayed in about that range until 1945 In 1945 1946, the bond market in England, as in America, celebrated the peace by one final sharp thrust upward.

1-14

the CRU would yield Eq. 1-14 in place of Eq. 1-9, which appears unbalanced and confusing, at least to the beginning student, compared to

Open It Up!

H R CH2 C Y H CH2 C*

The market reached new high prices in America, but in England it stopped 14 points short of its nineteenth-century highs In America this final crest of the wave seemed to be in part a natural expression of market optimism In England it was based on the official policy of a new Labour government and was enforced by every monetary tool Rising bond prices, however, did not catch the fancy of English investors or speculators Consols were forced up from 811 2, or 306%, in 1945 to a high of 995 8, or 251%, in 1946 They had not touched par since 1900, and they did not quite touch par in 1946 The government floated a new issue of 21 2% undated Treasury stock at 100, the Daltons, which were said to be preferable to redeemable consols because they could not be redeemed until 1975.

1-9

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