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Equation 1-9 has the repeating unit written the same way on both sides, while Eq. 1-14 has the repeating unit reversed on the right side relative to what it is on the left side. Before proceeding one needs to mention Chemical Abstracts (CA), a journal published by the American Chemical Society, that abstracts the world s chemical literature and has developed its own nomenclature rules. The CA rules are generally very close to the IUPAC rules, but there are some differences. Most of the differences are not important at the level of the discussions in this book. One difference that needs to be mentioned is the placement of locants. CA does not place locants immediately before the part of the name to which they apply. Thus, the CA name for the rst subunit in XV is 2,4-pyridinediyl instead of pyridine2,4-diyl. The difference between IUPAC and CA is also seen in the placement of locants in naming vinyl monomers such as CH2 CHCH2 CH3 . The IUPAC name is but-1-ene; the CA name is 1-butene. Most chemists tend to follow the CA placement of locants for small molecules. This text will generally follow the IUPAC rule for locants for CRU subunits, but the CA rule for monomers.

In 1946 began the long retreat of the English bond market, which lasted, with occasional cyclical interruptions, until 1974 English monetary policy maintained very low short-term rates until 1952 and attempted to support the bond market Nevertheless, long-term investors turned their backs on government bonds They missed the attraction of the potential capital gains that they had enjoyed after the Napoleonic Wars and of the high yields that they had enjoyed after World War I In 1947, consols were back to 80 In 1948 consols declined to 741 2, to yield 336% In 1949, the pound was devalued, and consols declined to 651 8, to yield 384% In 1950, the market did a little better In 1951, however, consols were down to 601 8, to yield 416% In 1952, there was a revival of monetary orthodoxy.

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Special terminology based on trade names has been employed for some polymers Although trade names should be avoided, one must be familiar with those that are rmly established and commonly used An example of trade-name nomenclature is the use of the name nylon for the polyamides from unsubstituted, nonbranched aliphatic monomers Two numbers are added onto the word nylon with the rst number indicating the number of methylene groups in the diamine portion of the polyamide and the second number the number of carbon atoms in the diacyl portion Thus poly(hexamethylene adipamide) and poly(hexamethylene sebacamide) are nylon 6,6 and nylon 6,10, respectively Variants of these names are frequently employed The literature contains such variations of nylon 6,6 as nylon 66, 66 nylon, nylon 6/6, 6,6 nylon, and 6-6 nylon Polyamides from single monomers are denoted by a single number to denote the number of carbon atoms in the repeating unit.

The SA-5 opens exactly the same as the SA-2 described in the prior project. Take a look back if it s unfamiliar.

Poly(Ecaprolactam) or poly(6-aminocaproic acid) is nylon 6 In far too many instances trade-name polymer nomenclature conveys very little meaning regarding the structure of a polymer Many condensation polymers, in fact, seem not to have names Thus the polymer obtained by the step polymerization of formaldehyde and phenol is variously referred to a phenol formaldehyde polymer, phenol formaldehyde resin, phenolic, phenolic resin, and phenoplast Polymers of formaldehyde or other aldehydes with urea or melamine are generally referred to as amino resins or aminoplasts without any more speci c names It is often extremely dif cult to determine which aldehyde and which amino monomers have been used to synthesize a particular polymer being referred to as an amino resin More speci c nomenclature, if it can be called that, is afforded by indicating the two reactants as in names such as urea formaldehyde resin or melamine formaldehyde resin.

A similar situation exists with the naming of many other polymers Thus the polymer XXVII is usually referred to as the polycarbonate from bisphenol A or polycarbonate The.

Short-term rates were deliberately raised for the first time in twenty-one years as part of an official attack on inflation and in defense of the monetary reserves The bank rate was put up from 2% to 4%, and the government issued new 41 4% bonds, to yield 431% Consols declined to 55, to yield 455% The market was again in a high range of yields, similar to the range of the 1920 s and above the range of any other extended period since 1820 These proved to be the low prices and high yields for three years to come In 1953 and 1954, there was an interim period of easier money coinciding.

different polymer molecules aggregate with each other This offers the ability to combine the properties of two very different polymers into one block copolymer The exception to this behavior occurs infrequently when the tendency for cross-aggregation between A and B blocks is the same as for self-aggregation of A blocks with A blocks and B blocks with B blocks Most commercial utilizations of copolymerization fall into one of two groups One group consists of various statistical (usually random) copolymers in which the two repeating units possess the same functional group The other group of commercial copolymers consists of block copolymers in which the two repeating units have different functional groups There are very few commercial statistical copolymers in which the two repeating units have different functional groups.

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