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Therefore w can be determined for any fluid from Tc, PC,and a single vapor-pressure measurement made at T, = 07 Values of w and the critical constants T,, PC,and V, for a number of fluids are listed in App B The definition of w makes its value zero for argon, krypton, and xenon, and experimental data yield compressibility factors for all three fluids that are correlated by the same curves when Z is represented as a function of T, and P, This is the basic premise of the following three-parameter theorem of corresponding states:

All fluids having the same value of w , when compared at the same T, and Pryhave about the same value of 2, and all deviate from ideal-gas behavior to about the same degree

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Although one may solve explicitly for its three roots, the generic cubic equation of state, Eq (341), is in practice far more commonly solved by iterative procedures10Convergence problems are most likely avoided when the equation is rearranged to a form suited to the solution for a particular root For the largest root, ie, a vapor or vapor-like volume, Eq (341) is multiplied through by (V - b ) / R T It can then be written:

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+ eb)(V + a b )

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Solution for V may be by trial, iteration, or with the solve routine of a software package An initial estimate for V is the ideal-gas value R T / P For iteration, this value is substituted on the right side of Eq (346) The resulting value of V on the left is then returned to the right side, and the process continues until the change in V is suitably small An equation for Z equivalent to Eq (346) is obtained through the substitution V = Z R T I P In addition, the definition of two dimensionless quantities leads to simplification Thus,

These substitutions into Eq (346) yield:

TABLE 12-1

(349)

This project s main routine is actually the MyApplication_Startup application event, from the ApplicationEvents.vb source code file. (That s one that you will have to use the Show All Files button to see.) To build the connection object at startup, add the following code to the end of that event handler.

Equations (347) and (348) in combination with Eqs (342) and (343) yield:

'O~uch procedures are built into computer software packages for technical calculations With these packages one can solve routinely for V in equations such as (341) with little thought as to how it is done

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